Identify major product 'P' formed in the following reaction.

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CONCEPT:

Friedel-Crafts Acylation

  • Friedel-Crafts acylation is a reaction where an acyl group (RCO-) is introduced to an aromatic ring (such as benzene) using an acyl chloride (RCOCl) and a Lewis acid (usually AlCl3).
  • This reaction is an electrophilic aromatic substitution in which the acyl group replaces a hydrogen atom on the aromatic ring.
  • The AlCl3 acts as a catalyst and helps in the generation of the acylium ion (RCO+), which is a highly electrophilic species that attacks the aromatic ring.

EXPLANATION:

  • In the given reaction:

    C6H6 + RCOCl → C6H5CO-R

  

    • The acyl chloride (RCOCl) reacts with AlCl3 to form the acylium ion (RCO+), which then attacks the benzene ring.
  • The mechanism of the reaction involves:
    • Generation of the acylium ion (RCO+) by the interaction of acyl chloride with AlCl3.
    • Attack of the acylium ion on the benzene ring to form the intermediate complex.
    • Loss of a proton from the intermediate complex results in the final product, an aryl ketone (C6H5CO-R).

Therefore, the major product 'P' formed in the reaction is an aryl ketone (C6H5CO-R).

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