Which one of the following metals can be extracted using carbon as reducing agent?

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UPSC NDA-II (General Ability) Official Paper-I (Held On: 03 Sept, 2023)
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  1. Zinc
  2. Silver
  3. Gold
  4. Aluminum

Answer (Detailed Solution Below)

Option 1 : Zinc
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Detailed Solution

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The Correct answer is Zinc.

Key Points

  • Zinc can be extracted using carbon as a reducing agent in a process known as reduction. In metallurgy, carbon, often in the form of coke, is used to reduce metal oxides to pure metal by removing oxygen.
  • The extraction process for zinc involves heating zinc oxide (ZnO) in the presence of carbon (C). The chemical reaction is:
    • ZnO(s) + C(s) → Zn(s) + CO(g)
  • This method is effective because zinc is moderately reactive, and carbon acts as a strong reducing agent capable of removing oxygen from zinc oxide at high temperatures.
  • Blast furnaces are often used for this reduction process, where the temperature is sufficiently high to facilitate the reaction between zinc oxide and carbon.
  • The conversion of zinc oxide to zinc metal and carbon monoxide illustrates the fundamental principles of redox reactions (reduction-oxidation), where carbon is oxidized and zinc is reduced.

Additional Information

  • Silver: It is typically extracted through hydrometallurgical or pyrometallurgical processes like leaching and smelting. Carbon is generally not used as a reducing agent for silver extraction.
  • Gold: This noble metal is extracted via hydrometallurgy methods such as cyanidation. Due to its low reactivity, carbon plays no role in gold extraction processes.
  • Aluminum: Extracted from bauxite ore through the Hall-Héroult process, which involves electrolysis of molten alumina. Carbon cannot reduce aluminum oxide effectively due to aluminium's high reactivity.
  • The choice of reducing agent in metal extraction primarily depends on the metal's reactivity. Less reactive metals can be reduced using carbon, whereas more reactive metals require electrolytic reduction.
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