Question
Download Solution PDFThe correct order of ligands arranged in increasing field strength.
- Cl– < – OH < Br– < CN–
- F– < Br– < I– < NH3
- Br– < F– < H2O < NH3
- H2O < – OH < CN– < NH3
Answer (Detailed Solution Below)
Option 3 : Br– < F– < H2O < NH3
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Detailed Solution
Download Solution PDFCONCEPT:
Ligand Field Strength (Spectrochemical Series)
- The spectrochemical series arranges ligands in order of increasing field strength (ability to split the d-orbitals of the central metal ion).
- Common ligands have the following approximate order from weakest to strongest:
- I– < Br– < Cl– < F– < OH– < H2O < NH3 < CN–
Explanation:-
- Comparing the experimental order with the given options, the third option is:
- Br– < F– < H2O < NH3
- This matches well with the experimental order and the known spectrochemical series.
- Experimental order Br– < F– < H2O < NH3
CONCLUSION:
The correct answer is Br– < F– < H2O < NH3
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