The effective activation energy for the reaction:
F1 Vinanti Teaching 04.09.23 D23

with the following potential energy versus reaction coordinate plot is
F1 Vinanti Teaching 04.09.23 D24

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CSIR-UGC (NET) Chemical Science: Held on (18 Sept 2022)
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  1. Ea - Ea' - Eb
  2. Ea + Eb - Ea'
  3. -Ea + Ea' - Eb
  4. Ea + Ea' - Eb

Answer (Detailed Solution Below)

Option 2 : Ea + Eb - Ea'
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Detailed Solution

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Concept:-

Activation energy:

  • ​It is the least amount of additional energy that a reacting molecule needs to produce a reaction product.
  • It is often referred to as the minimum energy needed to energise or activate molecules or atoms so that they can engage in a chemical reaction or transformation.
  • The addition of a catalyst during a chemical reaction alters activation energy.​
    • The presence of a catalyst lowers the activation energy of any reaction, hence it speeds up the rate of reaction
    • ​The catalyst provides an alternate pathway of lower activation energy.
  • ​It is measured in joules (J) and or kilojoules per mole (kJ/mol) or kilocalories per mole (kcal/mol).
  • It is denoted by Ea.

F1 Chemistry Mrunal 24.02.2023 D1

Explanation:-

 

  • The reaction is given by,

F1 Vinanti Teaching 04.09.23 D23

with the following potential energy versus reaction coordinate plot is
F1 Vinanti Teaching 04.09.23 D24

  • The effective activation energy for the reaction will be,

Ea + Eb - Ea'

Conclusion:-

Hence, the effective activation energy for the reaction with the following potential energy versus reaction coordinate plot is

Ea + Eb - Ea'

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