Which of the following statements is INCORRECT? The conductivity of electrolytic (ionic) solutions depends on:

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  1. the nature of the solute and its viscosity
  2. concentration of the electrolyte.
  3. The nature of the electrolyte added.
  4. Size of the ions produced and their solvation

Answer (Detailed Solution Below)

Option 1 : the nature of the solute and its viscosity
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Detailed Solution

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The correct answer is Option 1.

Key Points

  • The conductivity of electrolytic solutions primarily depends on the nature of the electrolyte added, not on the nature of the solute and its viscosity.
  • Electrolyte concentration affects the number of ions in the solution, which in turn influences conductivity.
  • The size of the ions produced and their solvation significantly impact the mobility of ions, thus affecting conductivity.
  • Viscosity influences the movement of ions but is not directly related to the nature of the solute.

Additional Information

  • Electrolytic Conductivity:
    • Electrolytic conductivity is a measure of a solution's ability to conduct electricity.
    • It is influenced by the presence and concentration of ions in the solution.
    • Conductivity increases with the number of ions present.
  • Ion Mobility:
    • Ion mobility refers to the speed at which ions move through a solution under the influence of an electric field.
    • Higher ion mobility leads to higher conductivity.
  • Solvation:
    • Solvation is the process of surrounding solute particles with solvent molecules.
    • It affects ion size and mobility, thus impacting the conductivity.
  • Viscosity:
    • Viscosity is a measure of a fluid's resistance to flow.
    • Higher viscosity can slow down ion movement, affecting conductivity.
    • However, it is the nature of the electrolyte that directly influences conductivity, not just viscosity.
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