In which defect equal number of cations and anions are missing from their lattice position?

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  1. Schottky defect
  2. Vacancy defect
  3. Impurity defect
  4. Frenkel defect

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Option 1 : Schottky defect
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CONCEPT:

Schottky defect:

  • Schottky defect is a type of point defect or imperfection in solids which is caused by a vacant position that is generated in a crystal lattice due to the atoms or ions moving out from the interior to the surface of the crystal.
  • Schottky defect in crystals is observed when equal numbers of cations and anions are missing from the lattice.
  • It is important that an equal number of cations and anions are missing, otherwise, the electrical neutrality of the crystal will get affected.

F2 Savita Engineering 25-7-22 D44

Additional Information

Defects/ Imperfections

Types of Defects / Imperfection

Point defects

(Zero-dimensional)

Vacancy Defect: It appears due to the missing of an atom from the lattice.

Frenkel defect: Atom occupies interstitial void in the lattice.

Schottky defect: It appears if, in a combination of cation and anion there is a vacancy.

Interstitial defect: It appears when a foreign atom occupies the interstitial site

Substitutional defect: It appears if a regular atom is replaced by another foreign atom.

Line defect or dislocations

(One-Dimensional)

Edge dislocation: If force is applied on 50% area and exceeds beyond a certain limit slipping of plane happens and an extra half-plane appears at dislocation line.

Screw dislocation: Formed by the shear stress that is applied to produce the distortion.

Surface defects

(Two-Dimensional)

Grain boundary defect: Due to the orientation mismatch at the grain boundary the bond length is more and can be easily broken.

Tilt boundary defect: When the orientation mismatch at the grain boundary is 0.5° - 1° then grain boundaries are called tilt boundaries.

Therefore, in Schottky defect, equal numbers of cations and anions are missing from their lattice positions.

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