Question
Download Solution PDFIn which defect equal number of cations and anions are missing from their lattice position?
Answer (Detailed Solution Below)
Detailed Solution
Download Solution PDFCONCEPT:
Schottky defect:
- Schottky defect is a type of point defect or imperfection in solids which is caused by a vacant position that is generated in a crystal lattice due to the atoms or ions moving out from the interior to the surface of the crystal.
- Schottky defect in crystals is observed when equal numbers of cations and anions are missing from the lattice.
- It is important that an equal number of cations and anions are missing, otherwise, the electrical neutrality of the crystal will get affected.
Additional Information
Defects/ Imperfections |
Types of Defects / Imperfection |
Point defects (Zero-dimensional) |
Vacancy Defect: It appears due to the missing of an atom from the lattice. Frenkel defect: Atom occupies interstitial void in the lattice. Schottky defect: It appears if, in a combination of cation and anion there is a vacancy. Interstitial defect: It appears when a foreign atom occupies the interstitial site Substitutional defect: It appears if a regular atom is replaced by another foreign atom. |
Line defect or dislocations (One-Dimensional) |
Edge dislocation: If force is applied on 50% area and exceeds beyond a certain limit slipping of plane happens and an extra half-plane appears at dislocation line. Screw dislocation: Formed by the shear stress that is applied to produce the distortion. |
Surface defects (Two-Dimensional) |
Grain boundary defect: Due to the orientation mismatch at the grain boundary the bond length is more and can be easily broken. Tilt boundary defect: When the orientation mismatch at the grain boundary is 0.5° - 1° then grain boundaries are called tilt boundaries. |
Therefore, in Schottky defect, equal numbers of cations and anions are missing from their lattice positions.
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